isophthalic acid/karijes

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Anion binding versus intramolecular hydrogen bonding in neutral macrocyclic amides.

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Although amide groups are important hydrogen-bond donors in natural and synthetic anion receptors, studies on structure-affinity relationships of amide-based macrocyclic receptors are still very limited. Therefore, we synthesized a series of macrocyclic tetraamides 5-8 derived from

Self-assembly of a series of cobalt(II) coordination polymers constructed from H2tbip and dipyridyl-based ligands.

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A series of interesting Co(II)-H(2)tbip coordination polymers incorporating different auxiliary ligands, {[Co(tbip)(bipy)(H(2)O)(3)] x 0.5(bipy) x H(2)O}(n) (1), [Co(tbip)(bipy)](n) (2), {[Co(3)(tbip)(3)(dpe)(3)] x 0.5(dpe) x 3 H(2)O}(n) (3), [Co(2)(tbip)(2)(dpe)(H(2)O)](n) (4),

Versatile Assembly of Metal-Coordinated Calix[4]resorcinarene Cavitands and Cages through Ancillary Linker Tuning.

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We propose a design strategy for assembly of metal-coordinated calix[4]resorcinarene cavitands and cages by tuning of the ancillary linkers. Assembly of newly functionalized cavitand with angular isophthalic acid analogs affords three intriguing metal-coordinated cavitands with deep cavities, 1a-1c.

Synthesis, structure, and characterization of three series of 3d-4f metal-organic frameworks based on rod-shaped and (6,3)-sheet metal carboxylate substructures.

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Three series of porous lanthanide metal-organic coordination polymers, namely [Cu(bpy)Ln(3)(ip)(5)(Hip)(H(2)O)] [Ln = Er (1a), Y (1b), Eu (1c); bpy = 2,2'-bipyridine, H(2)ip=isophthalic acid], [Cu(3)(bpy)(2)Ln(2)(ip)(6)(H(2)O)(5)] [Ln = Yb (2a), Gd (2b), Tb (2c)], and [Cu(3)Ln(2)(ip)(6)] [Ln = Eu

Self-assembly of dialkyltin(IV) moieties and aromatic dicarboxylates to complexes with a polymeric or a discrete trinuclear macrocyclic structure in the solid state and a mixture of fast interchanging cyclooligomeric structures in solution.

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It is well-known that the structures of trialkyltin(IV) carboxylates can be either monomeric, polymeric, or cyclooligomeric in the solid state. In contrast, all dialkyltin(IV) dicarboxylates characterized so far in the solid state have monomeric or polymeric structures, however, for some cases it

Guest molecule-responsive functional calcium phosphonate frameworks for tuned proton conductivity.

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We report the synthesis, structural characterization, and functionality (framework interconversions together with proton conductivity) of an open-framework hybrid that combines Ca(2+) ions and the rigid polyfunctional ligand 5-(dihydroxyphosphoryl)isophthalic acid (PiPhtA).

The next chapter in MOF pillaring strategies: trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms.

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A new pillaring strategy, based on a ligand-to-axial approach that combines the two previous common techniques, axial-to-axial and ligand-to-ligand, and permits design, access, and construction of higher dimensional MOFs, is introduced and validated. Trigonal heterofunctional ligands, in this case

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