tert butanol/dental caries

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Marginal adaptation of an etch-and-rinse adhesive with a new type of solvent in class II cavities after artificial aging.

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Log ind / Tilmeld

This in vitro study evaluated the marginal adaptation of etch-and-rinse adhesives. Standardized class II cavities were cut in 40 human molars with one proximal box limited within enamel and one proximal box extending into dentin. Teeth were assigned randomly to five groups (n = 8) and restored with

Absolute fundamental and overtone OH and OD stretching intensities of alcohols.

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Absolute intensities of the ΔvOH = 1 - 2 and ΔvOD = 1 - 3 transitions were determined for a range of alcohols (methanol, ethanol, 2-propanol, 1-propanol and tert-butanol) using conventional Fourier transform infrared (FTIR) spectroscopy. The intensities of the OH stretching transitions are stronger

Polymorphs and pseudopolymorphs of N,N'-dithiobisphthalimide.

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N,N'-Dithiobisphthalimide, C(16)H(8)N(2)O(4)S(2) (I), forms a wide range of polymorphs and solvates (pseudopolymorphs). When (I) is crystallized from methanol it yields a solvent-free polymorph (4), in Pna2(1) with Z' = 1, in which the molecules are linked into chains by a single C-H.O hydrogen

Critical factors in sonochemical degradation of fumaric acid.

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Log ind / Tilmeld

The effects of critical factors such as Henry's Law constant, atmospheric OH rate constant, initial concentration, H2O2, FeSO4 and tert-butanol on the sonochemical degradation of fumaric acid have been investigated. The pseudo first-order rate constant for the sonochemical degradation of 1mM fumaric

Preliminary crystallographic analysis of the bacteriophage P22 portal protein.

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Portal proteins are components of large oligomeric dsDNA pumps connecting the icosahedral capsid of tailed bacteriophages to the tail. Prior to the tail attachment, dsDNA is actively pumped through a central cavity formed by the subunits. We have studied the portal protein of bacteriophage P22,

The relationship between enhanced enzyme activity and structural dynamics in ionic liquids: a combined computational and experimental study.

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Log ind / Tilmeld

Candida antarctica lipase B (CALB) is an efficient biocatalyst for hydrolysis, esterification, and polymerization reactions. In order to understand how to control enzyme activity and stability we performed a combined experimental and molecular dynamics simulation study of CALB in organic solvents

Heterogeneous reaction of gaseous ozone with aqueous iodide in the presence of aqueous organic species.

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Log ind / Tilmeld

The fast reaction of gaseous ozone, O(3)(g), with aqueous iodide, I(-)(aq), was found to be affected by environmentally relevant cosolutes in experiments using cavity ring-down spectroscopy (CRDS) and electrospray ionization mass spectrometry (ESIMS) for the detection of gaseous and interfacial

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