isoquinoline/hymenoxys rusbyi

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AiltTrialacha cliniciúlaPaitinní

Roghnaigh cineál sórtála

Leathanach 1 ó 16 torthaí

TfOH-promoted synthesis of 4,5-dihydrooxazolo[5,4- c]isoquinolines via formal [3 + 2] cycloaddition of 4-diazoisoquinolin-3-one and benzonitriles

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Logáil Isteach / Cláraigh

A facile and efficient method for the synthesis of novel 2-substituted 4-tosyl-4,5-dihydrooxazolo[5,4-c]isoquinolines from 4-diazoisoquinolin-3-ones and nitriles is reported. The reaction proceeded through a TfOH-promoted formal [3 + 2] cycloaddition and the products could be conveniently converted

A sensitive and selective liquid chromatography-tandem mass spectrometry method for simultaneous determination of five isoquinoline alkaloids from Chelidonium majus L. in rat plasma and its application to a pharmacokinetic study.

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Logáil Isteach / Cláraigh

Chelidonium majus L. is one of the most important medicinal plants of the family Papaveraceae. Its pharmacological effects have been primarily attributed to the presence of a number of alkaloids. In the present study, a sensitive and selective liquid chromatography-tandem mass spectrometry method

Endothelium-independent and endothelium-dependent vasorelaxation by a dichloromethane fraction from Anogeissus Leiocarpus (DC) Guill. Et Perr. (Combretaceae): possible involvement of cyclic nucleotide phosphodiesterase inhibition.

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Logáil Isteach / Cláraigh

Many traditional medicinal herbs from Burkina Faso are used to treat arterial hypertension (HTA). Among them, Anogeissus leiocarpus (A. Leiocarpus) which is well known and widely used in Burkina traditional medicine. Herein we assess the effects of dichloromethane fraction from A. leiocarpus stem

Synthesis, photophysical and electrophosphorescent properties of fluorene-based platinum(II) complexes.

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Logáil Isteach / Cláraigh

A series of platinum(II) complexes bearing tridentate cyclometalated C^N^N (C^N^N=6-phenyl-2,2'-bipyridine and π-extended R-C^N^N=3-[6'-(naphthalen-2''-yl)pyridin-2'-yl]isoquinoline) ligands with fluorene units have been synthesised and their photophysical properties have been studied. The fluorene

Luminescent cyclometalated dialkynylgold(III) complexes of 2-phenylpyridine-type derivatives with readily tunable emission properties.

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Logáil Isteach / Cláraigh

A novel class of luminescent dialkynylgold(III) complexes containing various phenylpyridine and phenylisoquinoline-type bidentate ligands has been successfully synthesized and characterized. The structures of some of them have also been determined by X-ray crystallography. Electrochemical studies

An NMR study of trans ligand influence in rhodium eta2 triphenyltin hydride complexes.

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Logáil Isteach / Cláraigh

The complex [Rh(O(2)Cisoq)(H)(SnPh(3))(PPh(3))(2)] (O(2)Cisoq = isoquinoline-1-carboxylate), characterized by x-ray crystallography, was used as a precursor to three-center bonded complexes [Rh(O(2)Cisoq)(eta(2)-HSnPh(3))(PPh(3))(4-Rpy)] (R = carbomethoxy, acyl, bromo, aldehyde, hydrogen, methoxy,

Porphyrins with exocyclic rings. 15.(1) synthesis of quino- and isoquinoporphyrins, aza analogues of the naphthoporphyrins.

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Logáil Isteach / Cláraigh

Porphyrins with fused isoquinoline and quinoline units have been prepared by the "3 + 1" methodology. 5-Nitroisoquinoline and 6-nitroquinoline condensed with ethyl isocyanoacetate in the presence of a phosphazene base to give isoquino- and quinopyrroles, respectively. Ester saponification and

Automated multiple development thin-layer chromatography for separation of opiate alkaloids and derivatives.

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Logáil Isteach / Cláraigh

There are three types of opiate alkaloids. First, the poppy alkaloids: morphine, codeine, thebaine, noscapine and papaverine; then, the semi-synthetic and synthetic derivatives used in therapy as antitussives and analgesics, such as pholcodine, ethylmorphine and dextromethorphan; at last narcotic

Sensitive and selective photoinduced-electron-transfer-based sensing of alkylating agents.

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Logáil Isteach / Cláraigh

Photoinduced-electron-transfer (PET)-based chemosensing is a very elegant way of reporting the presence of a guest species in solution. This method was successfully applied for the detection of different ionic species, such as cations, anions, and protons. Herein, we report on the application of the

Five solvates of a multicomponent pharmaceutical salt formed by berberine and diclofenac.

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Logáil Isteach / Cláraigh

A multicomponent pharmaceutical salt formed by the isoquinoline alkaloid berberine (5,6-dihydro-9,10-dimethoxybenzo[g]-1,3-benzodioxolo[5,6-a]quinolizinium, BBR) and the nonsteroidal anti-inflammatory drug diclofenac {2-[2-(2,6-dichloroanilino)phenyl]acetic acid, DIC} was discovered. Five solvates

Passing two strings through the same ring using an octahedral metal center as template: a new synthesis of [3]rotaxanes.

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Logáil Isteach / Cláraigh

Octahedral transition metal centers such as Fe(II), Co(II), and Co(III) have been used as templates in the construction of [3]pseudorotaxanes and [3]rotaxanes from various acyclic and macrocyclic fragments. The species obtained consist of a ring threaded by two string-like compounds. Such systems

Direct infusion ESI-IT-MSn alkaloid profile and isolation of tetrahydroharman and other alkaloids from Bocageopsis pleiosperma maas (Annonaceae).

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Logáil Isteach / Cláraigh

BACKGROUND The Annonaceae family is known as a promising abundant source of secondary metabolites, especially annonaceous acetogenins, terpenoids and isoquinoline-derived alkaloids. Although widely investigated from the phytochemical viewpoint, this family still presents some largely unexplored

Rupestrines A-D, alkaloids from the aerial parts of Corydalis rupestris.

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Logáil Isteach / Cláraigh

Phytochemical investigation of the dichloromethane extract of the dried aerial parts of Corydalis rupestris (Papaveraceae) resulted in the identification of four new isoquinoline alkaloids rupestrines A-D and one known isoquinoline alkaloid, namely, stylopine. The structures of these compounds were

Revealing the anti-tumoral effect of Algerian Glaucium flavum roots against human cancer cells.

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Logáil Isteach / Cláraigh

Glaucium flavum (G. flavum) is a plant from the Papaveraceae family native to Algeria where it is used in local traditional medicine to treat warts. G. flavum root crude alkaloid extract inhibited breast cancer cell proliferation and induced G2/M phase cycle arrest and apoptosis without affecting

Separation of the potential G-quadruplex ligands from the butanol extract of Zanthoxylum ailanthoides Sieb. & Zucc. by countercurrent chromatography and preparative high performance liquid chromatography.

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Logáil Isteach / Cláraigh

G-quadruplex DNA structure is considered to be a very attractive target for antitumor drug design due to its unique role in maintaining telomerase activities. Therefore, discovering ligands with high stability of G-quadruplex structure is of great interest. In this paper, pH-zone refining counter

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