methyl vinyl ketone/karijes

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Thermodynamic Stability of Structure II Methyl Vinyl Ketone Binary Clathrate Hydrates and Effects of Secondary Guest Molecules on Large Guest Conformation.

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Clathrate hydrates have received massive attention because of their potential application as energy storage materials. Host water frameworks of clathrate hydrates provide empty cavities that can capture not only small molecular guests but also radical species induced by γ-irradiation. In this work,

Inhalation toxicity studies of the alpha,beta-unsaturated ketones: ethyl vinyl ketone.

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The National Toxicology Program is conducting a chemical class study to investigate the structure-activity relationships for the toxicity of alpha,beta-unsaturated ketones. Ethyl vinyl ketone (EVK) was selected for study because it is a representative straight-chain aliphatic alpha,beta-unsaturated

Synergic Interplay Between Halogen Bond and Hydrogen Bond in the Activation of a Neutral Substrate in a Nanoconfined Space.

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The principle of the "amplified halogen bonding (XB) in a small space" is here exploited as a catalytic tool for the activation of a XB acceptor substrate in a nanoconfined environment. The inner cavity of the resorcinarene capsule has been equipped with a XB catalyst bearing an ammonium

Mono(NCN-pincer palladium)-metalloporphyrin catalysts: evidence for supramolecular bimetallic catalysis.

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The synthesis and catalytic properties of ditopic mono-pincer-mono-porphyrin complexes were investigated. The statistical Adler condensation reaction of 3,5-bis(methoxymethyl)-4-bromo-benzaldehyde, p-tolylaldehyde, and pyrrole, furnished an AB(3)-type tetraphenylporphyrin, containing three

Photolysis of 4-oxo-2-pentenal in the 190-460 nm region.

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We have studied the gas-phase photolysis of 4-oxo-2-pentenal by laser photolysis combined with cavity ring-down spectroscopy. Absorption cross sections of cis- and trans-4-oxo-2-pentenal have been measured in the 190-460 nm region. The product channel following 193, 248, 308, and 351 nm photolysis

Combustion in the future: The importance of chemistry

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Combustion involves chemical reactions that are often highly exothermic. Combustion systems utilize the energy of chemical compounds released during this reactive process for transportation, to generate electric power, or to provide heat for various applications. Chemistry and combustion are

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