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Metabolic engineering of 2-phenylethanol pathway producing fragrance chemical and reducing lignin in Arabidopsis.

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CONCLUSIONS Two 2-phenylethanol biosynthetic pathways were constructed into Arabidopsis ; 2-phenylethanol biosynthesis led to reduced rate of lignin biosynthesis and increased cellulose-to-glucose conversion in the transgenic plants. Lignin is the second most abundant biopolymer on the planet with

Immobilized Arabidopsis thaliana Hydroxynitrile Lyase-Catalyzed Retro-Henry Reaction in the Synthesis of (S)-β-Nitroalcohols

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Enantiopure β-nitroalcohols are versatile intermediates used in the synthesis of important pharmaceuticals and chiral synthons. In this article, immobilized Arabidopsis thaliana HNL (AtHNL)-catalyzed preparation of (S)-β-nitroalcohols from their racemic mixtures via retro-Henry reaction was studied.

Serratia odorifera: analysis of volatile emission and biological impact of volatile compounds on Arabidopsis thaliana.

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Bacteria emit a wealth of volatiles. The combination of coupled gas chromatography/mass spectrometry (GC/MS) and proton-transfer-reaction mass spectrometry (PTR-MS) analyses provided a most comprehensive profile of volatiles of the rhizobacterium Serratia odorifera 4Rx13. An array of compounds,

Preparation of (S)-β-nitro alcohols by a (R)-selective HNL via enantioselective C-C bond cleavage.

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Hydroxynitrile lyase (HNL) catalysed stereoselective synthesis of β-nitro alcohols is considered as an efficient biocatalytic approach. However, there exist only one (S)-selective HNL i.e. Hevea brasiliensis (HbHNL) to synthesize (S)-β-nitro alcohols from corresponding aldehydes. Further, HbHNL

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