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silandrin/silybum

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[Structure of silandrin and silymonin, two new flavanolignans from a white blooming Silybum marianum variety].

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Prijava Registriraj se
The structures of two flavanolignans, (-) silandrin and (+) silymonin, from a white flowering variety of Silybum marianum, have been elucidated as 3-desoxy-isosilybin and 3-desoxy-silydianin partly by spectroscopic investigations, partly by chemical transformation into other derivatives and their

New insight into the biosynthesis of flavanolignans in the white-flowered variant of Silybum marianum.

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Prijava Registriraj se
It has been demonstrated that besides the known flavanolignan constituents of the white-flowered variant of Silybum marianum, (-)-silandrin A (3a) and (-)-isosilandrin A (4a); their trans-benzodioxane diastereomers, (-)-silandrin B (3b) and (-)-isosilandrin B (4b), are also produced by the plant.

Structure elucidation and antioxidant activity of (-)-isosilandrin isolated from Silybum marianum L.

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Prijava Registriraj se
A regioisomer of the known flavanolignan (-)-silandrin (3a), named (-)-isosilandrin (8a), was isolated from the fruits of a white-flowered variant of Silybum marianum L. populated in Hungary. Its structure was established both by spectroscopic methods and total synthesis, and its absolute
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