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7 rezultatima
Substituent effect in the photochromism of two isomeric asymmetric diarylethenes having pyrrole and thiophene units.
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Two new asymmetric isomeric diarylethenes having pyrrole and thiophene units have been synthesized by one-pot reaction and characterized by single crystal X-ray diffraction analysis. The two prepared diarylethenes had disparate crystal structures, and they exhibited distinctly different photochromic
Thiophenylazobenzene - an alternative photoisomerization controlled by lone pair∙∙∙π interaction.
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Azoheteroarene photoswitches have attracted attention due to their unique properties. We present here the stationary photochromism and the ultrafast photoisomerization mechanism of thiophenylazobenzene (TphAB) - an alternative sulfur-based azoheteroarene design. TphAB demonstrates impressive fatigue
A photochromic prototype based on difurylperhydrocyclopentene with remarkable photoswitching behavior and in vivo application.
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A new strategy has been developed to synthesize difurylperhydrocyclopentene derivatives. The compound displays reversible photochromism in solution and thin-film. The results show that furan is superior to thiophene in terms of strong fluorescence, higher photocyclization conversion and cyclization
Effects of heteroaryl ring on the photochromism of asymmetrical diarylethenes containing a naphthalene group.
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Photochromic asymmetrical diarylethene derivatives 1o-4o bearing different benzo-five-membered heterocyclic rings were synthesized and characterized with single-crystal X-ray diffraction microscopy. The effects of heterocyclic ring on their properties including the photochromic behaviors in
Croconaine Rotaxane Dye with 984 nm Absorption: Wavelength-Selective Photothermal Heating.
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Croconaines are an emerging class of near-infrared dyes that are useful for various sensing, photothermal, optoelectronic, and photoacoustic applications. Previous work encapsulated a dumbbell-shaped croconaine dye whose structure contains two thiophene flanking units inside a tetralactam macrocycle
In situ preparation of highly fluorescent dyes upon photoirradiation.
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Photoswitchable or photoactivatable fluorescent dyes are potentially applicable to ultrahigh density optical memory media as well as super-resolution fluorescence imaging when the dyes are highly fluorescent and have large absorption coefficients. Here, we report on highly fluorescent photochromic
Tuneable thermal expansion of poly (3,4-ethylenedioxythiophene) polystyrene sulfonate.
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Linear coefficient of thermal expansion is calculated for a mixture of poly(3,4-ethylenedioxythiophene) and polystyrene sulfonate (PEDOT:PSS) using density functional theory and the Debye-Grüneisen model. The linear coefficient of thermal expansion is a key factor in thermal management (thermal
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