germanium/dichloromethane

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Beta-nitro derivatives of germanium(IV) corrolates.

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The reaction between germanium(IV) meso-triphenylcorrolates and nitrate salts affords the corresponding beta-nitro substituted corroles in good yield. Chromatographic separation of the crude reaction mixtures enables isolation of a mu-oxo dimer along with the corresponding monomers bearing a hydroxy

Photochemistry of Solid Films of the Neonicotinoid Nitenpyram.

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The environmental fates of nitenpyram (NPM), a widely used neonicotinoid insecticide, are not well-known. A thin solid film of NPM deposited on a germanium attenuated total reflectance (ATR) crystal was exposed to radiation from a low-pressure mercury lamp at 254 nm, or from broadband low pressure

Formation of Boron-Main-Group Element Bonds by Reactions with a Tricoordinate Organoboron L2PhB: (L = Oxazol-2-ylidene).

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The reactivity of L2PhB: (1; L = oxazol-2-ylidene) as well as its transition-metal (chromium and iron) complexes toward main-group substrates have been systematically examined, which led to the construction of B-E (E = C, Ga, Cl, H, F, N) bonds. The combination of 1 and triethylborane smoothly

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