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[Perfluoro-n-octane in orbital cavity after posterior vitrectomy and suture of eye perforating injury: case report].

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A case of a perfluoro-n-octane leakage into the orbital cavity after corneoscleral suture, scleral buckling and pars plana vitrectomy in an eye with perforating injury after trauma is reported for the first time. A previously healthy 39-year-old man was sent for ophthalmic evaluation one day after

Understanding n-Octane Behavior near Graphene with Scaled Solvent-Solute Attractions.

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We employ molecular dynamics simulations of n-octane near a layered graphene surface to study the related phenomena of solvation, density fluctuations, wettability, and structure and dynamics of n-octane molecules in the inhomogeneous interfacial environment. That solvation in bulk n-octane displays

Foreign body response within postoperative perfluoro-N-octane for retinal detachment repair: clinical features, grading system, and histopathology.

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OBJECTIVE To describe the clinical and histopathologic characteristics of inflammatory deposits occurring within intermediate duration postoperative perfluoro-n-octane (PFO) for inferior retinal detachment repair. METHODS Prospective interventional case series of consecutive patients with inferior

Intra-pulse laser absorption sensor with cavity enhancement for oxidation experiments in a rapid compression machine.

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A sensor based on a mid-IR pulsed quantum cascade laser (QCL) and off-axis cavity enhanced absorption spectroscopy (OA-CEAS) has been developed for highly sensitive concentration measurements of carbon monoxide (CO) in a rapid compression machine. The duty cycle and the pulse repetition rate of the

Selective Adsorption of n-Alkanes from n-Octane on Metal-Organic Frameworks: Length Selectivity.

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The liquid-phase adsorption of n-alkanes (from n-octane (C8) solvent) with different chain lengths was carried out over three metal-organic frameworks (MOFs), viz., metal-azolate framework-6 (MAF-6), copper-benzenetricarboxylate (Cu-BTC), and iron-benzenetricarboxylate (MIL-100(Fe)), and a

Tolerance of extended-term vitreous replacement with perfluoro-n-octane and perfluoroperhydrophenanthrene mixture (phenoctane).

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OBJECTIVE To improve the surface visibility of perfluoroperhydrophenanthrene, we added various percentages of perfluoro-n-octane. METHODS Twenty New Zealand white rabbit eyes underwent gas vitrectomy. One milliliter of balanced salt solution was injected into each Group 1 eye as control.

Experimental studies of tolerance to intravitreal perfluoro-n-octane liquid.

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Low viscosity perfluorocarbon liquids are useful adjuncts during vitreoretinal surgery. This study evaluates perfluoro-n-octane (PFnO) for intraoperative use by examining ocular tolerance in rabbits and pigs. Rabbits were treated with intravitreal placement of PFnO for 48 hours and were examined

Perfluorocarbon liquid in the management of retinal detachment with proliferative vitreoretinopathy.

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OBJECTIVE To describe the techniques and results of perfluoro-N-octane used during vitrectomy for managing retinal detachment with severe proliferative vitreoretinopathy (PVR). METHODS The authors retrospectively studied 223 consecutive patients who underwent vitreoretinal surgery for severe PVR

Evaluation of anterior segment tolerance to short-term intravitreal perfluoron.

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OBJECTIVE A study was performed to evaluate corneal and anterior segment toxicity from short-term (24-hour) intravitreal use of perfluoro-n-octane. METHODS Forty aphakic, vitrectomized eyes of pigmented rabbits underwent intravitreal injection of either 0.5 ml of perfluoro-n-octane (Perfluoron;

Thermodynamic Functions of Solvation of Hydrocarbons, Noble Gases, and Hard Spheres in Tetrahydrofuran-Water Mixtures.

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Thermodynamic solvation properties of mixtures of water with tetrahydrofuran at 298 K are studied. The Gibbs free energies and enthalpies of solvation of n-octane and toluene are determined experimentally. For molecular dynamics simulations of the binary solvent, we have modified a TraPPE-UA model

Structural requirements of para-alkylphenols to bind to estrogen receptor.

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Octyl- and nonylphenols in the environment have been proposed to function as estrogens. To gain insight into their structural essentials in binding to the estrogen receptor, a series of phenols with saturated alkyl groups at the para position, HO-C6H4-CnH2n+1 (n = 0-12), were examined for their

Intracrystalline transport resistances in nanoporous zeolite X.

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By applying pulsed-field gradient nuclear magnetic resonance (PFG NMR) in comparison to quasi-elastic neutron scattering (QENS), we sense by measurement of the diffusion of n-octane on different length scales, transport resistances in faujasite type X (which is isostructural with type Y and differs

A Non-catalytic Deep Desulphurization Process using Hydrodynamic Cavitation.

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A novel approach is developed for desulphurization of fuels or organics without use of catalyst. In this process, organic and aqueous phases are mixed in a predefined manner under ambient conditions and passed through a cavitating device. Vapor cavities formed in the cavitating device are then

Molecular origins of fluorocarbon hydrophobicity.

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We have undertaken atomistic molecular simulations to systematically determine the structural contributions to the hydrophobicity of fluorinated solutes and surfaces compared to the corresponding hydrocarbon, yielding a unified explanation for these phenomena. We have transformed a short chain

Hydrophobic Cobalt-Ethylimidazolate Frameworks: Phase-Pure Syntheses and Possible Application in Cleaning of Contaminated Water.

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Two highly porous Co-based metal-azolate frameworks (MAFs), MAF-5(Co) and MAF-6(Co), which are isostructural with MAF-5(Zn) and MAF-6(Zn), respectively, were first synthesized in high yield and purity at room temperature. The syntheses compared two mixing methods, slow and fast, using cobalt acetate

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