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delcosine/delphinium
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Alkaloids from Delphinium pentagynum.
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Aerial parts of a collection of Delphinium pentagynum Lam. from Niebla, Southern Spain, furnished one diterpene alkaloid, 2-dehydrodeacetylheterophylloidine, two norditerpene alkaloids, 14-demethyl-14-isobutyrylanhweidelphinine and 14-demethyl-14-acetylanhweidelphinine, the known alkaloids
Norditerpenoid alkaloids from the roots of Delphinium stapeliosum.
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From the roots of Delphinium stapeliosum three new norditerpenoid alkaloids, 14-demethyltuguaconitine (1), 14-deacetyl-14-isobutyrylnudicauline (2), and 14-deacetyl-14-isobutyrylajadine (3), and nine known norditerpenoid alkaloids, delbonine (4), methyllycaconitine (5), 14-deacetylnudicauline (6),
Diterpenoid Alkaloids from Delphinium caeruleum.
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A new minor diterpenoid alkaloid, caeruline, was isolated from DELPHINIUM CAERULEUM Jacq. ex Camb. Its structure was elucidated as 1 on the basis of spectral evidence. Along with this new compound, three known diterpenoid alkaloids were also isolated from this plant and identified as tatsiensine,
[Diterpenoid alkaloids from Delphinium kamaonense var. glabrescens].
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A new and a known diterpenoid alkaloid have been isolated from the root of Delphinium kamaonense var. glabrescens. The chemical structure of the new alkaloid, named glabredelphine, was established as 2(3)-dehydro-6-demethyl-18-demethoxy-delcosine by IR, MS, 1HNMR and 13CNMR spectral data. The known
Diterpenoid alkaloids from the roots of Delphinium scabriflorum.
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Chemical investigation of the CHCl(3) extracts from the roots of Delphinium scabriflorum has resulted in the isolation of a new diterpenoid alkaloid, 13-(2-methylbutyryl)azitine (1), along with 11 known alkaloids, delbine (2), 14-deacetyl-14-isobutyrylajadine (3), methyllycaconitine (4),
Norditerpenoid alkaloids from Delphinium species.
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From the aerial parts of four Delphinium species 11 known and 3 new norditerpenoid alkaloids have been isolated: from D. dissectum Huth: delavaine A/B, deoxylycoctonine, methyllycaconitine; new: 10-hydroxymethyllycaconitine; from D. excelsum Reichenb.: delcaroline, delectinine, delterine,
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