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phenylpropanoic acid/hymenoxys rusbyi
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The Hydrolysis of the Anhydride of 2-Cyano-2-phenylpropanoic Acid Triggers the Repeated Back and Forth Motions of an Acid-Base Operated Molecular Switch.
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This work has been aimed at making phenomenologically autonomous the otherwise step-wise operation of a catenane-based molecular switch, chemically triggered by the decarboxylation of 2-cyano-2-phenylpropanoic acid ( 2 ). Given that any amount of 2 in stoichiometric excess with respect to the
Potential chemosignals in the anogenital gland secretion of giant pandas, Ailuropoda melanoleuca, associated with sex and individual identity.
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With a combination of dichloromethane extraction and analysis by gas chromatography-mass spectrometry (GC-MS), we found 39 compounds (corresponding to 38 GC peaks) in the anogenital gland secretion (AGS) of captive adult giant pandas, Ailuropoda melanoleuca, during the non-mating season. In addition
Controlling the liberation rate of the in situ release of a chemical fuel for the operationally autonomous motions of molecular machines.
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Second-order rate constants of the aminolysis of 2-cyano-2-phenylpropanoic anhydride 3 by a series of N-methylanilines differently substituted in the aromatic moiety (4a-d) were measured in dichloromethane. The common reaction product of aminolysis is 2-cyano-2-phenylpropanoic acid 1, which is known
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