tetrahydrothiophene/carie dentaria

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Aquasonolysis of thiophene and its derivatives.

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The rate constants and products of the aquasonolysis of thiophene, tetrahydrothiophene, 2-methylthiophene, 2,5-dimethylthiophene, and 2-ethylthiophene have been investigated. The sonolysis of the selected compounds in aqueous solution follows pseudo-first-order kinetics. The aquasonolytical rate

alpha-TEPHOS: a cyclodextrin-derived tetraphosphine for multiple metal binding.

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The tetraphosphine 6(A),6(B),6(D),6(E)-tetradeoxy-6(A),6(B),6(D),6(E)-tetra(diphenylphosphinyl)-2(A),2(B),2(C),2(D),2(E),2(F),3(A),3(B),3(C),3(D),3(E),3(F),6(C),6(F)-tetradeca-O-methyl-alpha-cyclodextrin (alpha-TEPHOS) has been prepared in high yield by reacting

Synthesis, Characterization, and Properties of Organometallic Molecular Cylinders Bearing Bulky Imidazo[1,5-a]pyridine-Based N-Heterocyclic Carbene Ligands.

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The metal-controlled self-assembly of organometallic molecular cylinders from a series of imidazo[1,5-a]pyridine-based tris-NHC ligands is described in this report. The imidazo[1,5-a]pyridinium salts H₃ -L(PF₆ )₃ (L=4 a-4 c) were treated with 1.5 equivalents of

Synthesis and Biological Evaluation of New Tricyclic Dihydropyridine Based Derivatives on Potassium Channels.

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The present study reports a microwave-assisted method for the synthesis of twelve novel tricyclic 1,4-dihydropyridine derivatives in which dimethyl-substituted cyclohexane and / or tetrahydrothiophene rings are fused to the DHP ring. The structures of the compounds were confirmed by spectral methods

Solventless supramolecular chemistry via vapor diffusion of volatile small molecules upon a new trinuclear silver(I)-nitrated pyrazolate macrometallocyclic solid: an experimental/theoretical investigation of the dipole/quadrupole chemisorption phenomena.

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A comparative study on the tendency of a new trinuclear silver(I) pyrazolate, namely, [N,N-(3,5-dinitropyrazolate)Ag]3 (1), and a similar compound known previously, [N,N-[3,5-bis(trifluoromethyl)pyrazolate]Ag]3 (2), to adsorb small volatile molecules was performed. It was found that 1 has a

Three- and four-coordinate gold(I) complexes of 3,6-bis(diphenylphosphino)pyridazine: monomers, polymers, and a metallocryptand cage.

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The slightly yellow polymeric complexes [Au(2)Cl(2)(P(2)pz)(3)](n), 1 x 6CHCl(3), (P(2)pz is 3,6-bis(diphenylphosphino)pyridazine) and [[Au(2)(P(2)pz)(3)](PF(6))(2)](n), 2, are prepared by the stoichiometric reaction of AuCl(tht) (tht is tetrahydrothiophene) and P(2)pz in either dichloromethane or

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