4 תוצאות
Reactions of the molybdates Na(2)MoO4.2 H2O and (nBu(4)N)2[Mo2O7] with [[Ru(arene)Cl(2)](2)] (arene=C(6)H5CH3, 1,3,5-C6H3(CH3)(3), 1,2,4,5-C6H2(CH3)4) in water or organic solvents led to formation of the triple-cubane organometallic oxides [[Ru(eta(6)-arene)](4)Mo4O16], whose crystal and molecular
The synthesis and structural characterization of [Ru(eta(6)-p-cymene)(eta(2)-TRIPHOS)Cl][PF(6)] is described. The complex is a highly active, homogeneous arene hydrogenation catalyst that is selective toward the hydrogenation of aromatic rings in preference to alkenes, as demonstrated by the
Amine-functionalized mono- and diphosphines have been used to prepare a series of ruthenium complexes which exhibit a variety of coordination modes depending on the number of donors possessed by the ligands, the degree of amine methylation, the solvent system used, and the oxidation state of the
Bisamino(diphosphonite), p-C6H4{N{P(OC6H4C3H5-o)2}2}2 (1), was prepared by reacting p-C6H4{N(PCl2)2}2 with four equivalents of o-allylphenol in 85% yield. Compound 1 on treatment with [M(CO)4(HNC5H10)2] (M = Mo or W) gave cis-[{M(CO)4}2{p-C6H4{N(P(OC6H4C3H5-o)2)2}2}] (2, M = Mo; 3, M = W). The