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Cavity ring-down spectroscopy of ambient NO2 with quantification and elimination of interferences.

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Ambientdetection of NO2 by cavity ring-down spectroscopy is examined in the wavelength region near 405.23 nm, and possible interferences by particulates, water vapor, and carbon dioxide are characterized. Particulates can be efficiently removed by the use of a 0.45 microm fluoropolymer filter. Water

Jet-cooled rovibrational spectroscopy of methoxyphenols using two complementary FTIR and QCL based spectrometers.

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Methoxyphenols (MPs) are a significant component of biomass burning emissions which mainly exists in our atmosphere in the gas phase where they contribute to the formation of secondary organic aerosols (SOAs). Rovibrational spectroscopy is a promising tool to monitor atmospheric MPs and infer their

Intermolecular interactions between doxorubicin and β-cyclodextrin 4-methoxyphenol conjugates.

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Newly synthesized derivatives of β-cyclodextrin, mono(6-deoxy-6-(1-1,2,3-triazo-4-yl)-1-propane-3-O-(4-methoxyphenyl))β-cyclodextrin (1) and mono(6-deoxy-6thio(1-propane-3-O-(4-methoxyphenyl))) β-cyclodextrin (2) were designed to be receptors of the anticancer drug doxorubicin, which could

Curcumin inhibits lipoxygenase by binding to its central cavity: theoretical and X-ray evidence.

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Many lipoxygenase inhibitors including curcumin are currently being studied for their anti-carcinogenic properties. Curcumin is a naturally occurring polyphenolic phytochemical isolated from the powdered rhizome of the plant Curcuma longa that possesses anti-inflammatory properties and inhibits

Investigating the solid state hosting abilities of homo- and hetero-valent [Co7] metallocalix[6]arenes.

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A family of homo-valent [Co(II)(7)(OH)(6)(L(1))(6)](NO(3))(2) (1), [(MeOH)(2) is a subset of Co(II)(7)(OH)(6)(L(1))(6)](NO(3))(2) (2) (where L(1)H = 2-iminomethyl-6-methoxyphenol) and hetero-valent [(NO(3))(2) is a subset of Co(III)Co(II)(6)(OH)(6)(L(2))(6)](NO(3))·3MeCN (4) (where L(2)H =

Biocatalytic Properties and Structural Analysis of Eugenol Oxidase from Rhodococcus jostii RHA1: A Versatile Oxidative Biocatalyst.

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Eugenol oxidase (EUGO) from Rhodococcus jostii RHA1 had previously been shown to convert only a limited set of phenolic compounds. In this study, we have explored the biocatalytic potential of this flavoprotein oxidase, resulting in a broadened substrate scope and a deeper insight into its

Characterization of human S-adenosyl-homocysteine hydrolase in vitro and identification of its potential inhibitors.

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Human S-adenosyl-homocysteine hydrolase (SAHH, E.C.3.3.1.1) has been considered to be an attractive target for the design of medicines to treat human disease, because of its important role in regulating biological methylation reactions to catalyse the reversible hydrolysis of S-adenosylhomocysteine

Heterogeneous reaction of gaseous ozone with aqueous iodide in the presence of aqueous organic species.

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The fast reaction of gaseous ozone, O(3)(g), with aqueous iodide, I(-)(aq), was found to be affected by environmentally relevant cosolutes in experiments using cavity ring-down spectroscopy (CRDS) and electrospray ionization mass spectrometry (ESIMS) for the detection of gaseous and interfacial

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