13 rezultatet
A theoretical protocol to study the sensitization and emission mechanism in lanthanide compounds on the basis of multireference CASSCF/PT2 calculations is proposed and applied to [Eu(NO3)3(dppz-CN)] and [Eu(NO3)3(dppz-NO2)] compounds synthesized and characterized herein. The method consists of a
The adiabatic transition energies from the lowest triplet states of four Europium tris β-diketonate/phenantroline complexes have been determined in vacuo and in dicholomethane solution by the ΔSCF approach at the density functional theory level, using the PBE1PBE and the CAM-B3LYP hybrid
Osteosarcoma (OSA) is malignant bone tumor, occurring in children and adults, characterized by poor prognosis. Despite advances in chemotherapy and surgical techniques, the survival of osteosarcoma patients is not improving significantly. Currently, great efforts are taken to identify novel
La2O2S:Eu3+ nanocrystals (NCs) with a mean size of 18 nm are prepared by gel thermolysis. The morphology of the particles is hexagonal. The surface Eu3+ ions are first detected by time-resolved spectra in the 5D0 --> 7F1 region. Because the symmetry of the sites occupied by surface Eu3+ ions is
Potential low-cost sorbents of metals based on combined action of coal and chitosan have been investigated. Sorption of Cs, Co and Eu on oxidized coals in mixture with chitosan was studied as function of pH ( approximately 3-6) in batch experiments using radiotracer method. An improved sorption
The compound Na3SO4Cl X (X = Ce(3+), Eu(3+) or Dy(3+)) prepared by the wet chemical method was studied for its photoluminescence (PL) and energy transfer characteristics. The PL from Na3 SO4 Cl:Ce(3+) shows strong emission at 322 nm at an excitation of 272 nm. Therefore, an efficient Ce(3+) →
The vast majority of fluorochromes are organic in nature and none of the few existing chelates have been applied as histological tracers for localizing brain anatomy and pathology.
In this study we have developed and characterized a Europium chelate with the ability to fluorescently label normal and
The synthesis and characterization of two europium(III) complexes, [Eu(L)(H2O)]Cl and [Eu(L)(phen)(H2O)]Cl (L=N,N'-bis(salicylidene)-3,6-dioxa-1,8-diaminooctanato and phen=1,10-phenanthroline) are reported. Exciting the Eu(III) complexes with near-UV light resulted in sensitized red luminescence by
GaN/AIN structures made of GaN quantum dots (QDs) separated by AIN spacer layers, were doped with Europium by ion implantation. Rutherford Backscattering/Channelling measurements showed that Eu is incorporated mainly on near-substitutional cation sites within the superlattice region. Only slight
The purpose of this study was to investigate a specialized liposomal contrast agent for magnetic resonance imaging (MRI), as part of a program to examine infiltrating immune cells in lesions of experimental allergic encephalomyelitis (EAE). A potent investigational liposomal contrast agent,
A new halophosphor K3Ca2(SO4)3F activated by Eu or Ce and K3Ca2(SO4)3F:Ce,Eu co-doped halosulfate phosphor has been synthesized by the co-precipitation method and characterized for its photoluminescence (PL). The PL emission spectra of the K3Ca2(SO4)3F:Ce phosphor show emission at 334 nm when
The photoluminescence stability of lanthanide complex in aqueous media is a prerequisite for diagnostics probes. The combination of building blocks working in concert to facilitate host-guest structures is now considered state of the art in surpassing this roadblock, yet there still remains a
The components with soft nature in the metal halide perovskite absorber usually generate lead (Pb)0 and iodine (I)0 defects during device fabrication and operation. These defects serve as not only recombination centers to deteriorate device efficiency but also degradation