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7 резултати
Insight into the electronic structure, optical properties, and redox behavior of the hybrid phthalocyaninoclathrochelates from experimental and density functional theory approaches.
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An insight into the electronic structure of several hafnium(IV), zirconium(IV), and lutetium(III) phthalocyaninoclathrochelates has been discussed on the basis of experimental UV-vis, MCD, electro- and spectroelectrochemical data as well as density functional theory (DFT) and time-dependent DFT
Optical coatings in microscale channels by atomic layer deposition.
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High-aspect-ratio channels may be coated using atomic layer deposition (ALD) due to the unique self-limiting nature of the process, and this has been often demonstrated using deep reactive-ion etched trenches in silicon. However, for optical and microfluidic applications, many channels are
Rietveld refinement of langbeinite-type K(2)YHf(PO(4))(3).
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Potassium yttrium hafnium tris-(orthophosphate) belongs to the langbeinite-family and is built up from [MO(6)] octa-hedra [in which the positions of the two independent M sites are mutually occupied by Y and Hf in a 0.605 (10):0.395 (10) ratio] and [PO(4)] tetra-hedra connected via vertices into a
Quantum cascade laser-based measurement of metal alkylamide density during atomic layer deposition.
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An in situ gas-phase diagnostic for the metal alkylamide compound tetrakis(ethylmethylamido) hafnium (TEMAH), Hf[N(C(2)H(5))(CH(3))](4), was demonstrated. This diagnostic is based on direct absorption measurement of TEMAH vapor using an external cavity quantum cascade laser emitting at 979 cm(-1),
Crystal Structure and Physical Properties of the Cage Compound Hf 2 B 2-2δ Ir 5+δ
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Hf2B2-2δIr5+δ crystallizes with a new type of structure: space group Pbam, a = 5.6300(3) Å, b = 11.2599(5) Å, and c = 3.8328(2) Å. Nearly 5% of the boron pairs are randomly replaced by single iridium atoms
Is titanium tetrafluoride (TiF4) effective to prevent carious and erosive lesions? A review of the literature.
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The present review summarises the effects of titanium tetrafluoride (TiF(4)) on the development and progression of carious and erosive lesions. The mode of action of TiF(4) is due to the formation of an acid-stable surface layer, which provides mechanical protection to the surface, and to an
Improved broadband spectral selectivity of absorbers/emitters for solar thermophotovoltaics based on 2D photonic crystal heterostructures.
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We propose a novel heterostructure based on 2D photonic crystals as broadband selective absorbers/emitters for solar thermophotovoltaics. Alternating hafnium oxide (HfO2) and titanium oxide (TiO2) filled cylinder cavities with tetragonal lattices are embedded into antireflection-coated tungsten (W)
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