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dihydroxynaphthalene/kuoza kwa meno

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NakalaMajaribio ya klinikiHati miliki
9 matokeo

Preparation of cage-shaped hexakis(spiroborate)s.

Watumiaji waliosajiliwa tu ndio wanaweza kutafsiri nakala
Ingia / Ingia
In previous research studies, various types of prismatic cage-shaped molecular containers have been prepared and evaluated in terms of their guest inclusion properties. Basically, most of these molecular cages have a cationic or electron-deficient nature, and exhibit strong affinity mainly toward

Dual self-sorting by cucurbit[8]uril to transform a mixed micelle to vesicle.

Watumiaji waliosajiliwa tu ndio wanaweza kutafsiri nakala
Ingia / Ingia
A systematic study on the cucurbit[8]uril (CB[8]) assisted transformation of a mixed micellar system of CTAB and a viologen surfactant to vesicles is depicted. The micelle to vesicle transformation is assisted by a charge transfer complex mediated ternary complexation between the viologen group of

Molecular pop-up toy: a molecular machine based on folding/unfolding motion of alkyl chains bound to a host.

Watumiaji waliosajiliwa tu ndio wanaweza kutafsiri nakala
Ingia / Ingia
We have designed and synthesized a new type of molecular machine based on the folding/unfolding motion of an alkyl chain bound to a host, triggered by a redox stimulus. A guest molecule containing a viologen unit with a long alkyl chain 1(2+) and its one-electron reduced species 1 + . form very

A macrocyclic receptor containing two viologen species connected by conjugated terphenyl groups.

Watumiaji waliosajiliwa tu ndio wanaweza kutafsiri nakala
Ingia / Ingia
A macrocyclic receptor molecule containing two viologen species connected by conjugated terphenyl groups has been designed and synthesised. The single-crystal X-ray structure shows that the two viologen residues have a transannular NN separation of ca. 7.4 Å. Thus, the internal cavity dimensions are
Thermodynamic parameters for complexation of polyvalent cyclodextrin (CD) cation and anion with oppositely charged guests have been determined in D2O containing 0.02 M NaCl by means of 1H-NMR spectroscopy. Protonated heptakis(6-amino-6-deoxy)-beta-CD (per-NH3+-beta-CD) forms stable inclusion

X-ray structure of beta-cyclodextrin-2,7-dihydroxy-naphthalene.4.6 H(2)O: an unusually distorted macrocycle.

Watumiaji waliosajiliwa tu ndio wanaweza kutafsiri nakala
Ingia / Ingia
The inclusion complex beta-cyclodextrin.2,7-dihydroxynaphthalene.4.6 H(2)O crystallized in the monoclinic space group P2(1), with a=14.082(3), b=19.079(4), c=12.417(3) A, beta=109.28(3) degrees, V=3149.0(11) A(3), and Z=2. An X-ray study performed at room temperature shows that the crystal packing

From Packed "Sandwich" to "Russian Doll": Assembly by Charge-Transfer Interactions in Cucurbit[10]uril.

Watumiaji waliosajiliwa tu ndio wanaweza kutafsiri nakala
Ingia / Ingia
As the host possessing the largest cavity in the cucurbit[n]uril (CB[n]) family, CB[10] has previously displayed unusual recognition and assembly properties with guests but much remains to be explored. Herein, we present the recognition properties of CB[10] toward a series of bipyridinium guests
The reaction between [Mo(NO)(Tp)I(2)] {Tp(-) = hydrotris(3,5-dimethylpyrazol-1-yl)borate} and 2,7-dihydroxynaphthalene affords, as its major product, the binuclear complex [Mo(NO)(Tp)(2,7-O(2)C(10)H(6))](2). The reaction appears to proceed under kinetic control so that shorter reaction times afford

Reversible deformation-formation of a multistimuli responsive vesicle by a supramolecular peptide amphiphile.

Watumiaji waliosajiliwa tu ndio wanaweza kutafsiri nakala
Ingia / Ingia
A systematic study of the ternary complex formation process for aromatic amino acids using ucurbit[8]uril (CB[8]) and a viologen amphiphile shows that the affinity of the amino acid needs to be higher or in a comparable range to that of CB[8] for the amphiphile in order to form the ternary complex.
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