Intrinsically Conductive Polymer Fibers from Thermoplastic trans-1,4-Polyisoprene.

Herein, we report a new strategy to prepare conductive polymer fibers to overcome the insurmountable weakness of current conductive polymer fibers. First, special thermoplastic polymers are processed into polymer fibers using a conventional melt-spinning process, and then the nonconductive polymer fibers are converted into intrinsically conductive polymer fibers. Using this new strategy, intrinsically conductive polymer fibers have been prepared by melt spinning low-cost thermoplastic trans-1,4-polyisoprene and doping with iodine, which can be as fine as 0.01 mm, and the resistivity can be as low as 10(-2) Ω m. Moreover, it has been found that drawing can improve the orientation of trans-1,4-polyisoprene crystals in the fibers and, thus, the conductivity of the conductive polymer fibers. Therefore, conductive fibers with excellent conductivities can be prepared by large drawing ratios before doping. Such conductive polymer fibers with low cost could be used in textile, clothing, packing, and other fields, which would benefit both industry and daily life. The newly developed method also allows one to produce conductive polymers of any shape besides fibers for antistatic or conductive applications.