Natural Product Communications 2015-Dec
Lycopodium Alkaloids from Diphasiastrum complanatum.
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One new lycopodine-type Lycopodium alkaloid, dehydroisofawcettiine N-oxide (1) and eleven known analogues (2-12) were isolated from the whole plant of Diphasiastrum complanatum. The new structure was established on the basis of spectroscopic methods, including 2D NMR techniques. The absolute configurations of 2 and its new N-oxide derivative (1) were deduced by chemical transformation combined with Cotton effects in their electronic circular dichroism (ECD) spectra.