A new flavonol diglycoside, rhamnocitrin-3-O-α-L-rhamnopyranosyl-(1-->6)-β-D-galactopyranoside, was isolated from the leaves of Ventilago Africana, in addition to 11 known flavonoids. Their structures were determined by spectroscopic methods including 1D- and 2D-NMR, and HR-ESI-MS analysis. The